Toye is a graduate of Sociology from the Lagos State University. A 2008 product of the Lagos Business School, Advanced Management Programme AMP. He is an Associate Member of the Chartered Institute of Personnel Management of Nigeria and an Affiliate Member of the Chartered Institute of Personnel Development of UK. He holds a Post Graduate Certificate in Strategic Human Resource Management from University of Roehampton UK.

He joined UAC of Nigeria PLC. UACN PLC. in 2001 as a Management Trainee, where he held several positions: Staff Admin. & Training Manager, Logistics Manager in Grand Cereals Limited-a subsidiary of UACN PLC. from 2002 to 2007, Human Resource Manager CAP PLC. a subsidiary of UACN PLC. From 2007 to 2010, Compensation & Industrial Relations Manager from 2010 to 2011, Resourcing & Development Manager, from 2011 to 2018 and Organizational Change Manager from 2018 to 2019 all in the Group HR Department of UACN PLC. Corporate Centre and Head, Human Resources for UPDC PLC. from 2019 to 2020.

He had a brief stint with Integrated Automotive Services, a subsidiary of TSL

Logistics Limited as Workshop Project Coordinator in 2020.